成型温度对PBX装药内部质量及性能的影响

针对压制成型的PBX炸药装药，选择CT无损检测、巴西实验和扫描电镜检测等技术，对比研究了室温和加热两种温度下压制成型的炸药装药内部质量、静态力学性能和细观破坏形式。结果表明，加热压制有利于改善炸药装药的内部质量，可避免产生初始损伤，且提高了装药的力学性能。细观尺度上，室温压制成型的装药主要发生界面脱黏破坏，加热压制成型装药的主要破坏形式是穿晶断裂。     

Profiling hot isostatically pressed canister–wasteform interaction for Pu-bearing zirconolite-rich wasteforms

Zirconolite-rich full ceramic wasteforms designed to immobilize Pu-bearing wastes were produced via hot isostatic pressing (HIP) using stainless steel (SS) and nickel (Ni) HIP canisters. A detailed profiling of the elemental compositions of the major and minor phases over the canister–wasteform interaction zone was performed using scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDS) characterization. Bulk sample analyses from regions near the center of the HIP canister were also conducted for both samples using X-ray diffraction and SEM-EDS. The sample with the Ni HIP canister showed almost no interaction zone with only minor diffusion of Ni from the inner wall of the canister into the near-surface region of the wasteform. The sample with the SS HIP canister showed ∼100–120 μm of interaction zone dominated by high-temperature Cr diffusion from canister materials to the wasteform with the Cr predominantly incorporated into the durable zirconolite phase. We also examined, for the first time, changes to the HIP canister wall thickness caused by HIPing and demonstrated that no canister wall thinning occurred. Instead, in the areas examined, the canister wall thickness was observed to increase (up to ∼20%) due to the compression occurring during the HIP cycle. Further, only sparse formation of (Cr, Mn)-rich oxide particles were noted within the HIP canister inner wall area immediately adjacent to the ceramic material, with no evidence for reverse diffusion of ceramic materials. Though the HIP canister–wasteform interaction extends to ∼120 μm when using an SS HIP canister for the system investigated, this translates to <<1 vol.% for an industrial scale HIPed wasteform. Importantly, the HIP canister–wasteform interactions did not produce any obviously less durable phases in the wasteform or had any detrimental impact on the HIP canister properties.     

日本の寒地，北海道における2030年代の水稲生育への温暖化の影響予測とその対応(日语原文)

北海道では1980年代から2010年代まで，水稲圃場栽培期間である5–9月の気温は年代とともに上昇した。そこで，直近の2010年代（2010—2019年平均）と比べて， 2つの2030年代の予測気象から，既報の関係式より水稲生育を予測した。その結果，2030年代では2010年代に比べ，限界移植日（移植早限）が水稲栽培17地域の平均で8～9日早い。また，早限出穂期が1～5日早く，晩限出穂期が1～5日遅く，安全出穂期間が2～10日長い。出穂期は1～3日早い。出穂期から晩限出穂まで2～9日長いため，遅延型冷害の発生がやや少ない。生育期別気象は，出穂前24日以降30日間では生育が早いため平均気温が同じかやや低い。出穂前10日以降40日間および出穂期以降40日間では平均気温がやや高く，日射量はやや少ない。そのため，玄米収量は96～98％とやや低く，潜在収量性を示す気候登熟量示数は同じである。障害不稔発生に関係する穂ばらみ期冷害危険期の平均気温はわずかに低いかほぼ同じであるため，冷害発生の危険性は残る。一方，不稔発生をもたらす低温域の出現頻度には，地域間で差異がある。精米蛋白質含有率は同じであるが，アミロース含有率はやや低く，やや良食味である。米粒外観品質では被害粒歩合と着色粒歩合は一定の傾向がなく，未熟粒歩合はやや高い。精米白度は同じであるが，玄米白度はやや高い。以上の予測に対する技術的対応方向を示した。     

冷低压分离器油相系统铵盐垢下腐蚀风险的模拟预测

为探究某加氢装置高压换热器管束腐蚀泄漏原因，利用Aspen Plus工艺模拟软件计算了冷低压分离器油相（简称冷低分油）中水质量分数分别为1%,2%,3%时，冷低分油系统的露点温度、氯化铵结晶温度、氯化铵潮解点温度和相对湿度。结果表明：相较于经验的露点温度预测方法，通过引入潮解点、划分系统“湿环境”温度范围判断氯化铵垢下腐蚀风险区域的方法与实际腐蚀案例更为切合；在3种油相含水条件下，换热器管束存在氯化铵垢下腐蚀的“湿环境”温度范围分别为：50~103 ℃,50~161 ℃,50~176 ℃；随着油相中含水量的提高，“湿环境”腐蚀区域逐渐向高温部位迁移，预计铵盐导致的垢下腐蚀将会愈加严重。     

Influence of pressure and dwell time on pressure-assisted sintering of calcium cobaltite

Calcium cobaltite Ca₃Co₄O₉, abbreviated Co349, is a promising thermoelectric material for high-temperature applications in air. Its anisotropic properties can be assigned to polycrystalline parts by texturing. Tape casting and pressure-assisted sintering (PAS) are a possible future way for a cost-effective mass-production of thermoelectric generators. This study examines the influence of pressure and dwell time during PAS at 900°C of tape-cast Co349 on texture and thermoelectric properties. Tape casting aligns lentoid Co349. PAS results in a textured Co349 microstructure with the thermoelectrically favorable ab-direction perpendicular to the pressing direction. By pressure variation during sintering, the microstructure of Co349 can be tailored either toward a maximum figure of merit as required for energy harvesting or toward a maximum power factor as required for energy harvesting. Moderate pressure of 2.5 MPa results in 25% porosity and a textured microstructure with a figure of merit of 0.13 at 700°C, two times higher than the dry-pressed, pressureless-sintered reference. A pressure of 7.5 MPa leads to 94% density and a high power factor of 326 µW/mK² at 800°C, which is 11 times higher than the dry-pressed reference (30 MPa) from the same powder.     

Microstructure and mechanical properties of hot-pressed SiC nanofiber reinforced SiC composites

This study reports on the preparation and mechanical properties of a novel SiC_nf/SiC composite. The single crystal SiC nanofiber(SiC_nf) reinforced SiC ceramic matrix composites (CMC) were successfully fabricated by hot pressing the mixture of β-SiC powders, SiC_nf and Al–B–C powder. The effects of SiC_nf mass fraction as well as the hot-pressing temperature on the microstructure and mechanical properties of SiC_nf/SiC CMC were systematically investigated. The results demonstrated that the 15 wt% SiC_nf/SiC CMC obtained by hot pressing (HP) at 1850 °C with 30 MPa for 60 min possessed the maximum flexural strength and fracture toughness of 678.2 MPa and 8.33 MPa m^1/2, respectively. The nanofibers pull out, nanofibers bridging and cracks deflection were found by scanning electron microscopy, which are believed can strengthen and toughen the SiC_nf/SiC CMC via consuming plenty of the fracture energy. Besides, although the relative density of the prepared SiC_nf/SiC CMC further increased with the sintering temperature rose to 1900 °C, the further coarsend composites grains results in the deterioration of the mechanical properties for the obtained composites compared to 1850 °C.     

铌对取向硅钢冷轧组织织构的影响

采用光学显微镜(OM)、电子背散射衍射(EBSD)等研究了铌对取向硅钢冷轧过程中的组织与织构的影响。结果表明:含铌正火板和不含铌正火板经冷轧后都是条带状组织,但含铌冷轧板在宽度方向更窄。铌元素的存在对织构也具有优化作用,经过中间退火后,含铌冷轧板二次冷轧织构得到明显改善,相较于不含铌二次冷轧板拥有强度较低的旋转立方织构以及强度较高的{111}<112>织构,其取向密度最高可达12.460。     

等通道挤压纯铝的冷轧织构与组织演变

研究了冷轧形变量对等通道挤压纯铝的形变织构与显微组织的影响。结果表明：当形变量较小时，冷轧使挤压高纯铝的显微组织分布更加均匀。然而，随着形变量的增加，晶粒由等轴向纤维状转变。织构的演变规律为旋转立方织构和{111}<110>向冷轧织构（铜织构、黄铜织构和S织构）转变，同时出现了R织构。由此可见，等通道挤压变形对高纯铝的冷轧组织和织构存在一定的影响。     

Microstructure–mechanical property relationship in an Al–Mg alloy processed by constrained groove pressing-cross route

The constrained groove pressing-cross route process was implemented on a commercially annealed AA5052 alloy at room temperature, with up to two passes (strain of ～4.64) along the rolling direction and transverse direction. The results showed the formation of an ultrafine-grained structure with an average sub-grain/cell size in the 300–500?nm range. The indentation hardness and tensile strength increased significantly, up to ～75 and 105%, respectively, and became more homogenous with a uniform and isotropic trend, as compared to the annealed alloy. According to the Hall–Petch and Taylor models used, grain refinement and increasing dislocation density were proposed as the main strengthening mechanisms. Fractographic studies revealed a ductile-fracture behaviour, with a dimpled structure proportional to the UFG structure.